Nonlinear Parameter Estimation Using Interval Analysis

نویسندگان

  • Chao-Yang Gau
  • Mark A. Stadtherr
چکیده

The reliable solution of nonlinear parameter estimation problems is an important computational problem in chemical process engineering, both in on-line and off-line applications. Conventional solution methods may not be reliable since they do not guarantee convergence to the global optimum sought in the parameter estimation problem. We demonstrate here a technique, based on interval analysis, that can solve the nonlinear parameter estimation problem with complete reliability, providing a mathematical and computational guarantee that the global optimum is found. As an example, we consider the estimation of parameters in vapor-liquid equilibrium (VLE) models. Twelve VLE data sets are fit to the Wilson equation. Results indicate that several sets of published parameter values correspond to local optima only, with new globally optimal parameter values found by using the interval approach.

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تاریخ انتشار 1998